Pt 53.299 Pd 41.414 Rh 276.496 Au 129.523 Ag 1.835

Physical Properties of Precious Metals

BLOG #1    May -10-2024

Welcome to the inaugural post of “Precious Metals Mechanics by Ami Gur.” In this series, we embark on a journey through the intriguing world of precious metals, starting with an exploration of the

תמונה ללינקדאין עמי
תמונה ללינקדאין עמי

physical properties that can be accurately measured to ensure their authenticity. Understanding these fundamental properties is crucial, as it lays the groundwork for more detailed discussions on specific testing methods and equipment in future posts.

Multi-Faceted Testing Approach

Authenticating precious metals such as gold and silver involves more than a single test, primarily because different metals or alloys might exhibit similar characteristics, such as conductivity or density. However, it is highly unlikely for them to mimic multiple properties simultaneously. Employing at least two different tests can significantly enhance the accuracy of the authentication process, a practice strongly recommended in the industry.

Key Properties and Tests

Conductivity and Resistivity

Electrical conductivity in metals results from the movement of electrically charged particles. Specifically, the valence electrons, which reside in the outermost shell of an atom, facilitate the conduction of electric current due to their ability to move freely. Devices that measure conductivity, using either direct assessments or the eddy current effect, play a pivotal role in determining these properties.

Notable Tools:

Density and Specific Gravity

The density of a metal is a crucial metric for distinguishing between substances like gold and other visually similar metals. Density meters or specific gravity testers provide essential data for these assessments. The formula for density is 𝑑=𝑀𝑉, where 𝑑 is density, 𝑀 is mass, and 𝑉 is volume, typically expressed in grams per cubic centimeter (e.g., pure gold has a density of 19.3 g/cm³, and pure silver 10.5 g/cm³).

Notable Tool:

Magnetic Susceptibility

Precious metals are typically non-magnetic. Specialized tools used to detect any magnetic properties help identify the presence of impurities or other metals. Notably, gold and silver exhibit diamagnetic properties, meaning they develop a weak magnetic moment in the opposite direction to an applied magnetic field.

Tool Highlight:

  • MAGNETIC SENSOR FOR CHECKING GOLD BARS AND COINS

Spectroscopic Analysis

X-ray Fluorescence (XRF)

This technique utilizes X-rays to determine the elemental composition saritof metals quickly and reliably. XRF describes the process where high-energy radiation excites atoms, causing them to emit X-ray fluorescence radiation as they return to a stable state.

Laser-Induced Breakdown Spectroscopy (LIBS)

A high-energy laser targets the metal, creating a plasma on its surface. The emitted light spectrum, characteristic of the metal’s composition, is then analyzed.

Ultrasonic Testing

This method involves measuring the velocity of sound waves through metals to assess their homogeneity and thickness.

Notable Tool:

Color Analysis

The color of a metal can offer clues about its composition. Photometric or colorimetric tests analyze the surface color to ensure it matches the expected hues for specific metals.

Thermal Conductivity

Thermal conductivity, the ability of a substance to conduct heat, is measured in watts per meter kelvin (W/mK). This property is crucial for materials like gold and silver, known for their high thermal conductivity.

Notable Tool:

Microscopic Examination

High-resolution imaging tools such as scanning electron microscopes (SEM) or optical microscopes can reveal surface characteristics and imperfections, confirming the manufacturing process and authenticity.

Acoustic Testing

Devices like the “Brainir Mini-C Coin Clamper v3 Ping Test” assess the sound produced by metals, providing insights based on their acoustic properties.

Acid Testing

Although slightly destructive, acid tests use nitric acid and other reagents to visually determine metal purity. This method is less accurate but useful for differentiating gold karats, platinum, and pure silver.

Notable Tool:

Looking Ahead: Future Technologies

In the near future, we might see the development of innovative methods such as “smell” tests, which could detect subtle chemical reactions or molecular signatures unique to each metal. This first blog is just an overview of the main physical properties and tools. We will examine their limitations and learn how to use them properly to apply non-destructive tests for the authentication of precious metals products such as bullions and jewelry.

This comprehensive overview sets the stage for upcoming posts where we will delve deeper into each testing method, helping you to understand and employ these techniques effectively. Stay tuned!

How to Calculate the Theoretical Density of an Alloy – And Why It Matters

By Ami Gur – A.G. Metals Ltd. One of the most common mistakes made when evaluating alloys is calculating density by simply averaging the densities of the constituent metals according to their weight percentages. Although this approach appears logical, it is incorrect. Understanding how to calculate the theoretical density of an alloy is a valuable skill for metallurgists, refiners, quality engineers, and anyone working with precious metals. When combined with XRF analysis, density measurement provides another practical tool for verifying alloy composition.

A Practical Example

Recently, while evaluating a silver-aluminum alloy, I noticed that the cast ingots appeared unusually light. The first question was simple: Does the measured density support the declared composition of 30 wt% Silver and 70 wt% Aluminum? Like many engineers, the first instinct is often to calculate: 30% × Silver density + 70% × Aluminum density This calculation gives a completely incorrect result because density is not a property that can be averaged by weight fraction.

The Correct Formula

For alloys where composition is expressed in weight percent, the theoretical density is calculated as: ρ = 1 / [(w₁ / ρ₁) + (w₂ / ρ₂) + …] Where:
  • ρ = theoretical alloy density
  • w = weight fraction of each element
  • ρ = density of each pure metal

Example

Silver density: 10.49 g/cm³ Aluminum density: 2.70 g/cm³ Composition:
  • 30 wt% Silver
  • 70 wt% Aluminum
Calculation: Density = 1 / [(0.30 / 10.49) + (0.70 / 2.70)] Theoretical density = approximately 3.47 g/cm³ Not 5.0 g/cm³ as obtained from the incorrect weighted-average calculation.

Why Is This Important?

Knowing the theoretical density allows you to:
  • Verify whether an alloy composition is reasonable.
  • Compare measured density with theoretical density.
  • Detect excessive casting porosity.
  • Identify possible contamination or incorrect alloying.
  • Support XRF and laboratory analytical results.
  • Improve quality control during production and refining.
Density alone does not identify every alloy, but it is an excellent verification tool when used together with chemical analysis.

Practical Considerations

Measured density is often slightly lower than the theoretical value because of:
  • Casting porosity
  • Shrinkage cavities
  • Oxide inclusions
  • Internal voids
  • Measurement uncertainty
For example, a measured density of 3.30 g/cm³ for a theoretical value of 3.47 g/cm³ may simply indicate a few percent porosity rather than an incorrect composition.

Final Thoughts

Even after more than 30 years working with precious metals and materials engineering, I still enjoy discovering—or rediscovering—fundamental engineering principles that have practical value in everyday work. A simple density calculation will never replace laboratory analysis, but it can provide an additional piece of evidence when evaluating an unknown alloy. Sometimes, the oldest engineering tools remain among the most useful. Real data. Real experience. No fluff.